Reaction mechanisms for hydrogen
1) Surface reactions: Catalytic combustion of hydrogen on palladium
Evaluation:evaluated by comparison between simulated and experimentally determined catalytic ignition temperatures for stagnation point flows on an electrically heated palladium foil.
Reference: O. Deutschmann, R. Schmidt, F. Behrendt, J. Warnatz. Proc. Combust. Inst. 26 (1996) 1747-1754.
2) Surface reactions: Catalytic oxidation of hydrogen over rhodium
Evaluation: evaluated on steady-state experimental measurements in stagnation-point reactor over Rh/Al2O3 catalyst at 673 -873K; experimentally determined catalytic ignition temperatures for stagnation point flows of H2/O2mixtures; experimentally measured species profiles in annular flow reactor (320 – 970K). Surface kinetics is thermodynamically consistent for a temperature range 273 – 1273K.
Reference: C. Karakaya, O. Deutschmann, Kinetics of Hydrogen Oxidation on Rh/Al2O3 Catalysts Studied in a Stagnation-flow Reactor, Chemical Engineering Science, 89 (2012) 171-184.